Chem160 Principles of Inorganic Chemistry II 2004 MIT
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MIT
Principles of Inorganic Chemistry II 5.04 (Fall 2004) Level Undergraduate |
Carbon monoxide (CO) is a π accepting ligand. The bonding of CO to a metal has two components: σ bonding and π backbonding. (Illustration by MIT OCW.)
Course Highlights
This course features a full set of lecture notes.
Course Description
This course provides a systematic presentation of the chemical
applications of group theory with emphasis on the formal development of
the subject and its applications to the physical methods of inorganic
chemical compounds. The electronic structure of molecules will be
developed. Against this backdrop, the optical, vibrational, and
magnetic properties of transition metal complexes are presented and
their investigation by the appropriate spectroscopy is described.
Course Resources
Course Resources
Course Lecture Notes
| LEC # | TOPICS |
|---|---|
| 1 | Symmetry Elements and Operations (PDF) |
| 2 | Operator Properties and Mathematical Groups (PDF) |
| 3 | Similarity Transforms, Classes and Representations (PDF) |
| 4 | Characters and Character Tables (PDF) |
| 5 | Molecular Point Groups I (PDF) |
| 6 | Molecular Point Groups II (PDF) |
| 7 | LCAO and Hückel Theory I (PDF) |
| 8 | Hückel Theory II (PDF) |
| 9 | N-Dimensional Cyclic Systems (PDF) |
| 10 | From Molecular Orbitals to Bands (PDF) |
| 11 | Band Theory (PDF - 1.7 MB) |
| 12 | Frontier Molecular Orbitals: σ Ligands (PDF) |
| 13 | Frontier Molecular Orbitals: π Ligands (PDF - 1.0 MB) |
| 14 | ML6 σ Complexes (PDF) |
| 15 | ML6 π Complexes (PDF) |
| 16 | Angular Overlap Method and M-L Diatomics (PDF) |
| 17 | AOM for MLn Ligand Fields (PDF) |
| 18 | Spectrochemical Series (Oh) / Descent in Symmetry (PDF) |
| 19 | Multiply Bonded Metal-Ligand Complexes (PDF) |
| 20 | Sandwich Compounds (PDF) |
| 21 | Bent Cp Complexes (PDF) |
| 22 | Metal-Metal Bonding: Single Bonds (PDF) |
| 23 | Metal-Metal Bonding: Quadruple Bonds (PDF) |
| 24 | Spectroscopy Introduction (PDF) |
| 25 | Central Field Approximation (PDF) |
| 26 | One Electron Crystal Field Energies (PDF) |
| 27 | Many Electron States: Russell Saunders Coupling (PDF) |
| 28 | Atomic State Wave Functions and Energies (PDF) |
| 29 | Weak and Strong Field Approximations (PDF) |
| 30 | Tanabe Sugano Diagrams (PDF) |
| 31 | Electronic Selection Rules (PDF) |
| 32 | Vibrational Spectroscopy and the IR (PDF - 1.0 MB) |
| 33 | Normal Coordinate Analysis (PDF) |
*Some translations represent previous versions of courses.
Copyright 2007,
by the Contributing Authors.
Cite/attribute Resource.
administrator. (2009, May 03). Chem160 Principles of Inorganic Chemistry II 2004 MIT. Retrieved March 12, 2010, from Free University Courses OCW Courses OpenCourseWare Freeversity Foundation Web site: http://freeversity.org/science-and-mathematics/chemistry/chem160-principles-of-inorganic-chemistry-ii-fall.
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